Pore-scale investigation of brine evaporation and salt precipitation in fractured porous media
Abstract
Understanding salt precipitation during evaporation in fractured porous media is essential for predicting pore-structure evolution, fracture permeability changes, and leakage miti gation. In fractured systems, brine transport occurs in both fracture and matrix domains, resulting in complex interactions. Using X-ray microtomography, this study investigated the mechanisms of brine evaporation and salt precipitation in such media. The results revealed two distinct stages of salt migration: (I) Evaporation and capillary transport, and (II) salt precipitation and accumulation. In Stage I, fractures acted as preferential gas pathways, exhibiting lower brine saturation, while the matrix retained higher saturation due to stronger capillarity. Residual brine films on particle surfaces within the fracture sustained evaporation and enabled capillary backflow from the matrix, further increasing brine concentration. In Stage II, once solubility limits were exceeded, salt crystals formed in the fracture, inducing additional capillary suction that drew more brine from the matrix and promoted further salt deposition. Increasing the gas flow rate limited brine migration toward the fracture center, thereby reducing salt accumulation in the fracture. At low flow rates, capillary replenishment from the matrix dominated over evaporation, sustaining continuous brine supply and extensive salt deposition throughout the fracture. At high flow rates, evaporation prevailed, restricting brine transport and confining salt accumulation mainly to the fracture-matrix interface. Across all conditions, salt precipitation progressively reduced effective pore sizes in both fracture and matrix, with implications for fracture permeability evolution.
Document Type: Original article
Cited as: Susanto, W., Nasir, M., Wang, B., Sin, S., Patmonoaji, A., Matsushita, S., Suekane, T. Pore-scale investigation of brine evaporation and salt precipitation in fractured porous media. Capillarity, 2026, 18(2): 68-82. https://doi.org/10.46690/capi.2026.02.03
DOI:
https://doi.org/10.46690/capi.2026.02.03Keywords:
Fractured porous media, salt precipitation, capillary backflow, evaporation, capillarity, X-ray microtomographyReferences
Akindipe D, Saraji S, Piri M. Salt precipitation during geological sequestration of supercritical CO2 in saline aquifers: A pore-scale experimental investigation. Advances in Water Resources, 2021, 155: 104011.
Bachu S. CO2 storage in geological media: Role, means, status and barriers to deployment. Progress in Energy and Combustion Science, 2008, 34: 254-273.
Bernal JD, Mason J. Packing of spheres: Co-ordination of randomly packed spheres. Nature, 1960, 188: 910-911.
Blunt MJ. Multiphase Flow in Permeable Media: A Pore Scale Perspective. Cambridge University Press, 2017.
Bogdanov II, Mourzenko VV, Thovert JF, et al. Two phase flow through fractured porous media. Physical Review E, 2003, 68: 026703.
Bultreys T, Boone MA, Boone MN, et al. Fast laboratory-based micro-computed tomography for pore scale research: Illustrative experiments and perspectives on the future. Advances in Water Resources, 2016, 95: 341-351.
Chen X, Hu R, Zhou C, et al. Capillary-driven backflow during salt precipitation in a rough fracture. Water Resources Research, 2024, 60: 1-20.
Dashtian H, Shokri N, Sahimi M. Pore-network model of evaporation-induced salt precipitation in porous media: The effect of correlations and heterogeneity. Advances in Water Resources, 2018, 112: 59-71.
Gostick JT. Versatile and efficient pore network extraction method using marker-based watershed segmentation. Physical Review E, 2017, 96: 023307.
Grimm Lima M, Schädle P, Green CP, et al. Permeability impairment and salt precipitation patterns during CO2 injection into single natural brine-filled fractures. Water Resources Research, 2020, 56: e2020WR027213.
He D, Jiang P, Xu R. Pore-scale experimental investigation of the effect of supercritical CO2 injection rate and surface wettability on salt precipitation. Environmental Science & Technology, 2019, 53: 14744-14751.
Hu Y, She Y, Patmonoaji A, et al. Effect of capillary number on morphological characterizations of trapped gas bubbles: Study by using micro-tomography. International Journal of Heat and Mass Transfer, 2020, 163: 120508.
Intergovernmental Panel on Climate Change (IPCC). Climate Change 2022: Mitigation of Climate Change (Sixth Assessment Report, AR6). Cambridge University Press, 2022.
Joekar-Niasar V, Hassanizadeh SM. Analysis of fundamentals of two-phase flow in porous media using dynamic pore-network models: A review. Critical Reviews in Environmental Science and Technology, 2012, 42: 1895-1976.
Kézdi Á. Soil Physics: Selected Topics. Amsterdam, Netherlands, Elsevier, 2013.
Miri R, van Noort R, Aagaard P, et al. New insights on the physics of salt precipitation during injection of CO2 into saline aquifers. International Journal of Greenhouse Gas Control, 2015, 43: 10-21.
Miri R, Hellevang H. Salt precipitation during CO2 storage: A review. International Journal of Greenhouse Gas Control, 2016, 51: 136-147.
Nasir M, Kaito K, Patmonoaji A, et al. Three-dimensional pore-scale observation of drying process of porous media. International Journal of Heat and Mass Transfer, 2022, 196: 123299.
Nasir M, Li Z, Mahardika MA, et al. Pore-scale investigation of wettability effects on drying process of three dimensional porous medium. International Communications in Heat and Mass Transfer, 2023, 140: 106527.
Norouzi Rad M, Shokri N, Sahimi M. Pore-scale dynamics of salt precipitation in drying porous media. Physical Review E, 2013, 88: 032404.
Ott H, De Kloe KD, Marcelis F, et al. Injection of supercritical CO2 in brine-saturated sandstone: Pattern formation during salt precipitation. Energy Procedia, 2011, 4: 4425-4432.
Patmonoaji A, Muharrik M, Hu Y, et al. Three-dimensional fingering structures in immiscible flow at the crossover from viscous to capillary fingering. International Journal of Multiphase Flow, 2020, 122: 103147.
Patmonoaji A, Mahardika MA, Nasir M, et al. Stereolithography 3D printer for micromodel fabrications with comprehensive accuracy evaluation by using microtomography. Geosciences, 2022, 12: 183.
Pruess K, Müller N. Formation dry-out from CO2 injection into saline aquifers: Effects of solids precipitation and their mitigation. Water Resources Research, 2009, 45: W03402.
Raats PAC. Dynamics of fluids in porous media. Soil Science Society of America Journal, 1973, 37: 206-208.
Roy R. Evaporation-induced salt precipitation in porous media and the governing solute transport. West Lafayette, Purdue University, 2022.
Schindelin J, Arganda-Carreras I, Frise E, et al. Fiji: An open-source platform for biological-image analysis. Nature Methods, 2012, 9: 676-682.
Seidell A. Solubilities of inorganic and organic compounds. Agronomy Journal, 1928, 20: 1234-1245.
Shahidzadeh N, Schut MFL, Desarnaud J, et al. Salt stains from evaporating droplets. Scientific Reports, 2015, 5: 10335.
Shahidzadeh-Bonn N, Rafai S, Bonn D, et al. Salt crystallization during evaporation: Impact of interfacial properties. Langmuir, 2008, 24: 8599-8605.
Shokri N. Pore-scale dynamics of salt transport and distribution in drying porous media. Physics of Fluids, 2014, 26: 012004.
Shokri N, Lehmann P, Or D. Liquid-phase continuity and solute concentration dynamics during evaporation from porous media: Pore-scale processes near vaporization surface. Physical Review E, 2010, 81: 046308.
Sin S, Imai S, Mahardika MA, et al. Three-dimensional visualization of Rayleigh-Bénard convection in porous media. Advances in Water Resources, 2024, 186: 104666.
Suekane T, Saito Y, Jiang L. Non-wetting phase saturation after drainage from the wetting-phase-filled porous media. Journal of Fluid Science and Technology, 2015, 10: JFST0014.
Sun L, Liu Y, Ren J, et al. Salt precipitation and pore structure changes during CO2 injection into porous media. Journal of Cleaner Production, 2025, 505: 145446.
Susanto W, Nasir M, Mahardika MA, et al. Investigating the effects of flow rate on pore-scale mass transfer and salt spatial distribution in the drying process of porous media using X-ray microtomography. International Communications in Heat and Mass Transfer, 2025, 166: 109113.
Wang G, Liu Y, Xiong W, et al. An improved non-local means filter for color image denoising. Optik, 2018, 173: 157-173.
Wu H, Fang C, Wu R, et al. Drying of porous media by concurrent drainage and evaporation: A pore network modeling study. International Journal of Heat and Mass Transfer, 2020, 152: 118718.
Yan L, Niftaliyev R, Voskov D, et al. Dynamics of salt precipitation at pore scale during CO2 subsurface storage in saline aquifer. Journal of Colloid and Interface Science, 2025, 678: 419-430.
Zhang D, Kang Y, Selvadurai APS, et al. Experimental investigation of the effect of salt precipitation on the physical and mechanical properties of a tight sandstone. Rock Mechanics and Rock Engineering, 2020, 53: 4367-4380.
Zhang S, Liu H. Porosity-permeability relationships in modeling salt precipitation during CO2 sequestration: Review of conceptual models and implementation in numerical simulations. International Journal of Greenhouse Gas Control, 2016, 52: 24-31.
Zhao B, MacMinn CW, Juanes R. Wettability control on multiphase flow in patterned microfluidics. Proceedings of the National Academy of Sciences of the United States of America, 2016, 113: 10251-10256.
Downloads
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Author(s)

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.